Absorbance kinetics of dye-doped systems with photochemical first order kinetics

Author(s)
Romano Rupp, Baoli Yao, Yuan Zheng, Neimule Menke, Yingli Wang, Weibin Dong, Wei Zhao, Yi Chen, Meigong Fang, Jing-Jun Xu, Martin Fally
Abstract

Usually it is assumed that the absorbance decays exponentially with the time dependence of the photochemical kinetics. Although this is true in the limiting case of vanishing absorbance, deviations are to be expected for realistic samples, because the local photochemical kinetics slows down with increasing initial absorption and penetration depth of the radiation. We analyze the time dependence of the absorbance originating from photochemical first order kinetics of dye-doped systems and compare the data with experimental results published by Lafond et al. and Tork et al. for fulgides doped in different polymer matrices.

Organisation(s)
Physics of Functional Materials
External organisation(s)
Chinese Academy of Sciences (CAS), Nankai University
Journal
Physica Status Solidi. B: Basic Research
Volume
244
Pages
2138-2150
No. of pages
13
ISSN
0370-1972
DOI
https://doi.org/10.1002/pssb.200642374
Publication date
2007
Peer reviewed
Yes
Austrian Fields of Science 2012
103008 Experimental physics
Portal url
https://ucris.univie.ac.at/portal/en/publications/absorbance-kinetics-of-dyedoped-systems-with-photochemical-first-order-kinetics(fd155df9-5d50-4da3-987f-7fa922766c5c).html